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Principles of polymerization
Abstract
Introduction 1; Types of polymers and polymerizations 1; Nomenclature of polymers 9; Linear, branched, and crosslinked polymers 17; Molecular weight 19; Physical state 24; Applications of polymers 32; 2.
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Step polymerization 39; Reactivity of functional groups 40; Kinetics of step polymerization 44; Accessibility of functional groups 63; Equilibrium considerations 65; Cyclization versus linear polymerization 69; Molecular weight control in linear polymerization 74; Molecular weight distribution in linear polymerization 80; Process conditions 87; Multichain polymerization 101; Crosslinking 103; Molecular weight distributions in nonlinear polymerizations 114; Crosslinking technology 117; Step copolymerization 135; High-performance polymers 144; Inorganic and organometallic polymers 168; Dendritic (highly branched) polymers 174; Miscellaneous topics 180; 3. Radical chain polymerization 198; Nature of radical chain polymerization 199; Structural arrangement of monomer units 202; Rate of radical chain polymerization 204; Initiation 209; Molecular weight 236; Chain transfer 238; Inhibition and retardation 255; Determination of absolute rate constants 264; Energetic characteristics 271; Autoacceleration 282; Molecular weight distribution 289; Effect of pressure 292; Process conditions 296; Specific commercial polymers 300; Living radical polymerization 313; Other polymerizations 330; 4. Emulsion polymerization 350; Description of process 350; Quantitative aspects 356; Other characteristics of emulsion polymerization 363; 5. Ionic chain polymerization 372; Comparison of radical and ionic polymerizations 372; Cationic polymerization of the carbon-carbon double bond 374; Anionic polymerization of the carbon-carbon double bond 412; Block and other polymer architectures 436; Distinguishing between radical, cationic, and anionic polymerizations 443; Carbonyl polymerization 444; Miscellaneous polymerizations 449; 6. Chain copolymerization 464; General considerations 465; Copolymer composition 466; Radical copolymerization 487; Ionic copolymerization 506; Deviations from terminal copolymerization model 512; Copolymerizations involving dienes 521; Other copolymerizations 528; Applications of copolymerization 529; 7. Ring-opening polymerization 544; General characteristics 545; Cyclic ethers 548; Lactams 569; N-carboxy-α-amino acid anhydrides 578; Lactones 581; Nitrogen heterocyclics 586; Sulfur heterocyclics 588; Cycloalkenes 589; Miscellaneous oxygen heterocyclics 592; Other ring-opening polymerizations 594; Inorganic and partially inorganic polymers 595; Copolymerization 600; 8. Stereochemistry of polymerization 619; Types of stereoisomerism in polymers 620; Properties of stereoregular polymers 633; Forces of stereoregulation in alkene polymerizations 637; Traditional Ziegler–Natta polymerization of nonpolar alkene monomers 644; Metallocene polymerization of nonpolar alkene monomers 665; Other hydrocarbon monomers 682; Copolymerization 684; Postmetallocene: chelate initiators 685; Living polymerization 689; Polymerization of 1,3-dienes 689; Commerical applications 695; Polymerization of polar vinyl monomers 699; Aldehydes 703; Optical activity in polymers 704; Ring-opening polymerization 707; Statistical models of propagation 708; 9. Reactions of polymers 729; Principles of polymer reactivity 729; Crosslinking 737; Reactions of cellulose 745; Reactions of poly(vinyl acetate) 748; Halogenation 748; Aromatic substitution 750; Cyclization 751; Other reactions 752; Graft copolymers 752; Block copolymers 759; Polymers as carriers or supports 760; Polymer reagents 765; Polymer catalysts 768; Polymer substrates 771; Index 789; Contents V.
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SCAFF Q 325
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Testo disponibile anche in formato Ebook